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. 2019 Jan 23;9(2):19. doi: 10.3390/membranes9020019
4M four-phase Maxwell model
α permeability selectivity, -
αS solubility selectivity, -
αD diffusion selectivity, -
φ volume fraction, -
θ time-lag, s
AR aspect ratio, -
Barrer permeability unit, 10−10 cm3 (STP) cm cmHg−1·s−1·cm−2
BET Brunauer, Emmett and Teller method for the determination of the surface area
C concentration, mol m−3 or cm3(STP) cm−3
CHA framework type code of zeolite chabasite
Cytop ® poly(perfluoro-4-vinyloxy-1-butene)
D diffusivity, m2/s
dk kinetic diameter, Å
FEM finite element numerical modelling
FFV fractional free volume, -
Hyflon® AD co-polymers of tetrafluoroethylene and perfluoro-4-methoxy-1,3-dioxole
J flux, mol/(m2·s) or cm3(STP)/(cm3·s)
l membrane thickness, μm
MD molecular dynamics
MFI framework type code of zeolite ZSM-5
MMM mixed matrix membrane
MOF metal organic framework
Nafion® copolymers of tetrafluoroethylene and sulfonic acid terminated perfluorovinyl ethers
NELF non-equilibrium lattice fluid
NMR nuclear magnetic resonance
p pressure, Pa
P permeability, Barrer or Nm3·m·m−2·Pa−1·s−1
PF permeability of the dispersed phase, Barrer or Nm3·m·m−2·Pa−1·s−1
PM permeability of the continuous phase, Barrer or Nm3·m·m−2·Pa−1·s−1
PMMM permeability of the MMM, Barrer or Nm3·m·m−2·Pa−1·s−1
PALS positron annihilation lifetime spectroscopy
PFG-NMR pulsed field gradient NMR
S solubility, mol·m−3·Pa−1 or cm3(STP)·cm−3·Pa−1
Tc critical temperature, K
Tg glass transition temperature, K
PFP perfluorinated polymer
PIM polymer of intrinsic microporosity
SAPO-34 silicon aluminium phosphate of chasbasite (CHA) structure topology.
SEM scanning electron microscopy
Silicalite-1 pure SiO2 zeolite of ZSM-5 (MFI) structure topology
Teflon® polytetrafluoroethylene
Teflon® AF co-polymer of tetrafluoroethylene and perfluoro-2,2-dimethyl-1,3-dioxole
STP standard temperature and pressure