Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.
Sequential allylic alkylation catalyzed by by iridium and palladium complexes.
 |
Ir conditions: [Ir(cod)Cl]2 (2 mol%), L3 (4 mol%), TBD (10 mol%), LiBr (1 equiv), in THF at 25 °C.
Pd conditions: Pd2(dba)3 (5 mol%), ligand (12.5 mol%), TBAT (1.2 equiv), allyl carbonate (1.2 equiv), in THF at 25 °C.
