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(A) Biomimetic aliphatic C–H hydroxylation reactivity using non-heme iron catalysts Fe(TPA) and Fe(MEP). (B) Aliphatic C–H oxidations catalyzed by Fe(MEP) are stereospecific, and H2O18 labeling studies indicate that they proceed via iron carbonyls. (C) The first example of preparative oxidation catalyzed by a non-heme iron complex is in the epoxidation of terminal olefins.
