Table 1.
Time (h) | PES | PBS | PHS | ||||||
---|---|---|---|---|---|---|---|---|---|
Tm (°C) | ∆Hm (J/g) | Xc (%) | Tm (°C) | ∆Hm (J/g) | Xc (%) | Tm (°C) | ∆Hm (J/g) | Xc (%) | |
0 | 102.1 ± 0.8 | 49.2 ± 1.1 | 64.0 ± 1.4 | 105.1 ± 0.7 | 53.1 ± 1.5 | 48.2 ± 1.4 | 52.2 ± 0.8 | 57.0 ± 1.2 | 42.1 ± 0.9 |
2 | 101.9 ± 0.6 | 47.1 ± 1.2 | 62.1 ± 1.6 | 105.1 ± 0.8 | 51.9 ± 1.2 | 47.0 ± 1.1 | 52.0 ± 0.6 | 55.0 ± 1.6 | 40.8 ± 1.2 |
6 | 101.7 ± 0.6 | 45.8 ± 1.0 | 59.8 ± 1.3 | 105.0 ± 0.6 | 50.2 ± 1.7 | 45.9 ± 1.5 | 51.1 ± 0.6 | 54.2 ± 1.3 | 40.0 ± 1.0 |
8 | 101.0 ± 0.5 | 45.1 ± 1.2 | 59.2 ± 1.6 | 104.2 ± 0.4 | 46.8 ± 1.1 | 42.3 ± 1.0 | 51.1 ± 0.3 | 51.4 ± 2.2 | 38.1 ± 1.6 |
10 | 101.0 ± 0.5 | 42.8 ± 0.9 | 56.6 ± 1.2 | 104.1 ± 0.4 | 44.1 ± 1.5 | 39.8 ± 1.4 | 49.8 ± 0.3 | 50.0 ± 1.1 | 36.9 ± 0. 8 |
Time: referred to the degradation time of polyesters; Tm: melting temperature; ∆Hm: enthalpy of fusion. ,, 110, and 135 J/g for PES, PBS, and PHS, respectively [37].