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. 2018 Jan 18;10(1):90. doi: 10.3390/polym10010090

Table 1.

Thermal properties of the three polyester films before and after degradation for different times.

Time (h) PES PBS PHS
Tm (°C) Hm (J/g) Xc (%) Tm (°C) Hm (J/g) Xc (%) Tm (°C) Hm (J/g) Xc (%)
0 102.1 ± 0.8 49.2 ± 1.1 64.0 ± 1.4 105.1 ± 0.7 53.1 ± 1.5 48.2 ± 1.4 52.2 ± 0.8 57.0 ± 1.2 42.1 ± 0.9
2 101.9 ± 0.6 47.1 ± 1.2 62.1 ± 1.6 105.1 ± 0.8 51.9 ± 1.2 47.0 ± 1.1 52.0 ± 0.6 55.0 ± 1.6 40.8 ± 1.2
6 101.7 ± 0.6 45.8 ± 1.0 59.8 ± 1.3 105.0 ± 0.6 50.2 ± 1.7 45.9 ± 1.5 51.1 ± 0.6 54.2 ± 1.3 40.0 ± 1.0
8 101.0 ± 0.5 45.1 ± 1.2 59.2 ± 1.6 104.2 ± 0.4 46.8 ± 1.1 42.3 ± 1.0 51.1 ± 0.3 51.4 ± 2.2 38.1 ± 1.6
10 101.0 ± 0.5 42.8 ± 0.9 56.6 ± 1.2 104.1 ± 0.4 44.1 ± 1.5 39.8 ± 1.4 49.8 ± 0.3 50.0 ± 1.1 36.9 ± 0. 8

Time: referred to the degradation time of polyesters; Tm: melting temperature; ∆Hm: enthalpy of fusion. XC(%)=ΔHmΔHm0×100%,ΔHm0=76.4, 110, and 135 J/g for PES, PBS, and PHS, respectively [37].