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. 2018 Jan 31;10(2):136. doi: 10.3390/polym10020136

Table 1.

Porous iron(III)-based metal–organic frameworks (MOFs) employed as cationic promoted photoinitiators.

Organic linker Terephthalic acid Fumaric acid Terephthalic acid Azobenzene tetracarboxylic acid Trimesic acid
graphic file with name polymers-10-00136-i001.jpg graphic file with name polymers-10-00136-i002.jpg graphic file with name polymers-10-00136-i003.jpg graphic file with name polymers-10-00136-i004.jpg graphic file with name polymers-10-00136-i005.jpg
Cristalline structure graphic file with name polymers-10-00136-i006.jpg graphic file with name polymers-10-00136-i007.jpg graphic file with name polymers-10-00136-i008.jpg graphic file with name polymers-10-00136-i009.jpg graphic file with name polymers-10-00136-i010.jpg
Chemical formula Fe(OH)[C8O4H4]
nsolv
Fe3O(OH)(H2O)2
[C4O4H2]3 nsolv
Fe3O(OH)(H2O)2
[C8O4H4]3 nsolv
Fe3O(OH)(H2O)2
[C16O8N2H6]2 nsolv
Fe3O(OH)(H2O)2
[C9O6H3]2 nsolv
%Fe 23.6 (chains) 30.9 (trimers) 24.2 (trimers) 21.4 (trimers) 25.8 (trimers)
Flexibility Yes Yes Yes No No
Pore size (Å) 8.5 6.5 9 6
10
25 (5)
19 (8.6)
Particle size (µm) 2–3 5–9 0.06–0.10 0.5–0.7 0.1–0.4
0.05–0.10