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Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
Free radical vinyl polymerization of the monomer vinylidene fluoride to obtain PVDF. Different chain conformations of PVDF in the apolar α-phase and in the polar β- and γ-phases.