Skip to main content
. 2017 Nov 13;9(11):610. doi: 10.3390/polym9110610

Table 1.

Composition of the reaction mixtures for low conversion copolymerization of monomer systems: MAH/F8H2MA, MAH/BMA, BMA/F8H2MA, BMA/F8H2MA/MAH, DMA/F8H2MA/MAH (T = 65 °C).

mMAH (g) fMAH mBMA (g) fBMA mF8H2MA (g) fF8H2MA mDMA (g) fDMA mAIBN (g) mMEK (g) mHFX (g) CM (mol/L)
0.650 0.60 - - 2.34 0.400 - - 0.018 2.25 2.25 2.50
0.220 0.30 - - 2.77 0.700 - - 0.013 1.55 1.55 2.50
1.530 0.60 1.400 - - - - - 0.042 5.15 5.15 2.50
1.080 0.45 1.920 0.400 - - - - 0.040 4.90 4.90 2.50
- - 0.190 0.550 2.81 0.800 - - 0.011 1.32 1.32 2.50
- - 0.540 0.200 2.46 0.550 - - 0.014 1.70 1.70 2.50
0.360 0.33 0.525 0.450 2.00 0.330 - - 0.018 2.00 2.00 2.77
0.737 0.50 0.530 0.330 2.00 0.250 - - 0.025 3.00 3.00 2.50
3.680 0.75 1.240 0.250 2.00 0.075 - - 0.082 10.00 10.00 2.50
1.840 0.75 - 0.175 1.00 0.075 1.11 0.175 0.164 6.27 6.27 2.00
1.840 0.75 - - 1.00 0.075 1.11 0.175 0.164 12.54 - 2.00
1.715 0.21 - - 0.50 0.040 1.25 0.210 0.150 5.84 5.84 2.00
0.920 0.75 - - 1.00 0.150 0.32 0.100 0.082 3.13 3.13 2.00
2.760 0.90 - - 0.50 0.030 0.56 0.070 0.200 7.83 7.83 2.00
0.750 0.55 - - 1.00 0.315 1.11 0.315 0.091 3.48 3.48 2.00

MAH, maleic anhydride; BMA, n-butyl methacrylate; F8H2MA, 1H,1H,2H,2H-perfluorodecyl methacrylate; DMA, n-dodecyl methacrylate;, AIBN, 2,2′-azo-bis-isobutyronitrile; MEK, methyl ethyl ketone; HFX, 1,3-bis (trifluoromethyl) benzene; fi, molar fraction of monomer in reaction mixture; CM, total monomer concentration.