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. 2017 Jul 25;9(8):303. doi: 10.3390/polym9080303

Table 1.

Summary of the wearable sensors.

Sensor Type Sensing Element Substrate Electrode Active Material Working Voltage Sensing Range Sensitivity Flexibility Stretchability Reliability Reference
Temperature Human hand temperature PDMS or thin PVA Au Au 0.6 V 20~150 °C 1.9 Ohm K−1 - 100% - [42]
Temperature Temperature PDMS AgNW Graphene 10 V 30~100 °C Nonlinear resistance response - 50% 100 [31]
Temperature Endothelial layer Polyester fabric strip coated with PDMS Au Platinum (Pt) 0.8 V 0~120 °C 2.7 Ohm K−1 0.01% - - [54]
pressure Intraocular pressure (IOP) Parylene graphene-AgNW ecoflex (capacitive-type) - 5~150 mmHg - Bending radius: 3.1 μm 25% 10,000 cycles with 25% strain [32]
Pressure Cutaneous pressure Ecoflex Au Lead zirconate titanate (PbZr0.52Ti0.48O3, PZT) VG: 3.5 V VD: 0.1 V 0.005~10 Pa 1.36 μA Pa−1 14.8 mm bending radius 30% 1000 [3]
Pressure Touch PET or Polyurethane Conductive carbon fabric CNT/PDMS porous 0.1 V 0.25~100 kPa - 30 mm bending radius 30% 10 [39]
Pressure Artery wrist pulse or acoustic vibrations PDMS Au Au NWs 1.5 V 13 Pa~50 kPa 1.14 kPa−1 30 mm bending radius 25% 50,000 [36]
Pressure Pressure PDMS and Epoxy (SU8) Au or AgNW/graphene Graphene VG: 25 V VD: 0.1 V 250 Pa~3 Mpa 2.05 × 10−4 kPa−1 (below 500 kPa), 9.43 × 10−6 kPa−1 (above 500 kPa) - - 1000 [33]
Strain Facial expressions PDMS Polyurethane-PEDOT:PSS Single-walled carbon nanotubes 1 V 1.6~3.6%, 10~100% 62 (ΔR/R)/ε 3.60% 100% Minimum 50 cycles for bending, 1000 cycles for stretching [34]
Strain Heartbeats PDMS Graphene woven fabrics Graphene woven fabrics 1 V under 0.2~30% 1000 (ΔR/R)/ε - 30% - [86]
Strain Stretch and pressure PDMS Eutectic Gallium Indium Single-walled carbon nanotubes-Ecoflex - ~150% 0.004 (ΔC/C)/ε - 150% - [69]
Strain Joint movement (bending) Silicon elastomer (Dragonskin 10 + Thi-Vex silicon thickener + Slo-jo platinum silicon cure retarder) Silver wire Ionic fluid - silicon elastomer AC 5 V, 50~200 Hz ~700% 0.348 (ΔC/C)/ε - 700% minimum 20 cycles for stretching [92]
Strain Bending PDMS coated Polystyrene Silver paste ZnSnO3 nanowires 1.2 V ~0.33% 3740 (ΔI/I)/ε 0.33% No stretchability - [95]
Strain Lymphedema Silicon rubber (Solaris) Cu Cu-PI (capacitive-type) - 0~30% - - 30% - [160]
Strain Strain PET textile Carbon nanotube/reduced Graphene oxide ZnO Nanowire - Sensor limits of bacterium/μL - 3~5% - 100 bending cycles [83]
Gas O2 (oxygen) Porous PTFE (porous polytetrafluoroethylene) Au High-purity 1-butyl-1-methylpyrrolidinium bis (trifluoro-methylsulfonyl)imide −1.4V 0~21% 0.48 uA/% Can be bent either convex or concave - - [117]
Gas NO2 (nitrogen dioxide) PES (polyethersulfone) Cr/Au Graphene 30 V 0.5 to 40 ppm R/R0 = −40% (at 40 ppm N2) R/R0 = 5% under a bending strain of 1.4% - - [37]
Gas NO2 (nitrogen dioxide) Paper Au NaNO2 treated PbS CQD 4.1 V 0.5 to 50 ppm 0.41/ppm Bending angle of 70° - 7% decrease in response under 5000 cyclic bending tests (Bending angle of 50°) [114]
Gas Volatile compouds (ammonia, acetic acid) Plastic substrate Cr/Au Polypyrrole (Ppy) (functionalized by carboxyl group) −0.1~0.1 V 0.1~100 ppm - Bending angle: 15° - - [163]
Gas Dimethyl methylphosphonate (DMMP) PI or PDMS or parylene Graphene-AgNW Graphene (functionalized by polypyrrole (Ppy)) 0.1 V 5~25 ppm - - 20% 1000 cycles with 5% strain [18]
Gas H2S, C2H5OH, H2 PI Ti/Au Graphene oxide - Graphene limits of bacterium/μL Toluene, Acetone, CO Ethanol at 20 PPM, Acetone at 20 ppm, H2S, H2 at 5–20 ppm A 30° bending angle - 104 bending cycles [175]
Bio Protein (Concanavalin A, Con A) PET or PDMS or parylene Graphene-AgNW Graphene (functionalized by mannosyl-pyrene) 0.1 V 1 mg/mL - Bending radius: 27 μm (bending strain: 2.59%) 20% - [12]
Bio Bacteria (E. coli, S. aureus, H. pylori) Silk fibroin film Cr/Au graphene (functionalized by antimicrobial peptides (AMPs)) - Detection limits of bacterium/μL 100~108 CFU/mL - - - [159]
Bio Lactate Temporary transfer tatto paper, GORETEX Ag/AgCl, conductive carbon lactate oxidase(LOx) 0.05 V 1 mM to 25 mM 644.2 nA/mM at RT, 0.916 μA/mM at 37 °C Bending angle of 90° stretched at ~10% The bending/stretching test: 10 times [136]
Bio D-glucose Polyimide film (2 μm) Cr/Au In2O3, glucose oxidase 0.2~0.8 V 100 μM to 4 mM - Bending radius of 837 (0.078~0.082%) - - [40]
Bio Glucose PDMS, Polyimide, Parylene Graphene/AgNW Graphene, glucose oxidase 0.1 V 1 μM~10 mM - - ∆R < 6% at 25% tensile strain (5000 cycles) ∆R ~20% at 10,000 cycles of stretching [32]
Bio Glucose, Lactate PDMS - Enzyme and chromogenic reagent - Glucose: 0~25 mM Lactage: 0~100 mM - 5 cm bending radius Strain 30% - [177]
Bio Salivary Uric acid PET Ag/AgCl Prussian-blue-graphite - Mouthguard limits of bacterium/μL 2.45 μA/mM - - - [29]
Ion Chloride, H+ PDMS - Enzyme and chromogenic reagent - Chloride: 0~625 μM pH: 5.0~8.5 - 5 cm bending radius Strain 30% - [177]
Ion Na+, K+ Textile Ecoflex-containing Ag/AgCl ink, MWCNT Multi-walled carbon nanotubes (functionalized by carboxylic acid) - Physiological range of human sweat (10~110 × 103 M NaCl, 1~8 × 103 M KCl) 54.1 ± 1.5 mV/log [Na+], 56.9 ± 1.6 mV/log [K+] Bending angle of 180° 100 % (uniaxial stretching) No sensitivity degradation at linear strain of 75% during 60 min at a speed of 1 mm/s [122]
Ion Na+, K+ PET (polyethylene terephthalate) Cr/Au, Ag/AgCl Multi-walled carbon nanotubes 3.7 V 1 mM KCl and 10 mM NaCl (working condition) 62.5 mV/log [Na+], 59.5 mV/log [K+] Radius of curvature 1.5 cm - No sensitivity degradation by bending radius of 1.5 cm over 60 cycles [38]
Ion H+ Poly (methylmethacrylate) Graphite Graphene −0.4~0.4 V pH 5~8 17 mV/pH Radius of curvature: 1.2 cm 0.04 No significant change in the electrical response (mobility values remained constant) as a result of bending to radii of curvature as small as 0.7 cm (estimated bending-induced strain: 0.6%) [126]
Ion Ca2+, H+ PET (polyethylene terephthalate) Ag/AgCl reference electrode Polyaniline (PANI) - Typical physiological [Ca2+] variations (e.g., 1 mM to 0.5 mM), pH 4~7 32.7 mV/log [Ca2+], 62.5 mV/pH - - - [127]