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aReaction conditions: 1a (0.2 mmol), B2(pin)2 (0.3 mmol), 4-cyanopyridine (0.3 mmol), alkene (0.4 mmol), MTBE (1.0 mL), DIPEA (0.2 mmol), 24 h, 80 °C. Isolated yield. Me = methyl, Et = ethyl, tBu = tert-butyl.
