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. Author manuscript; available in PMC: 2020 Feb 6.
Published in final edited form as: J Am Chem Soc. 2019 Jan 25;141(5):2087–2096. doi: 10.1021/jacs.8b11868

Figure 2.

Relative and absolute stereoselection in 2-propanolmediated reductive couplings of allenes with fluoral hydrate via concentration-dependent diastereoselectivity.a

Figure 2.

a Diastereoselectivity determined by 19F NMR of crude reaction mixtures. Enantioselectivities were determined by chiral stationary phase HPLC analysis. Yields of material isolated by silica gel chromatography. See Supporting Information for further experimental details.