Scheme 2. Schematic Representation of the Creation of Artificial Metalloenzymes by Using the Stop Codon Suppression Methodology for the in Vivo Incorporation of BpyAla and the Catalyzed Friedel–Crafts Alkylation Reaction.
*Sign of the optical rotation of the major enantiomer was erroneously assigned in the original report. Adapted with permission from ref (32). Copyright 2015 The Royal Society of Chemistry.