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. Author manuscript; available in PMC: 2019 Jul 11.
Published in final edited form as: J Am Chem Soc. 2018 Jun 27;140(27):8551–8562. doi: 10.1021/jacs.8b04153

Table 4.

Aryl Bromide Scope for ortho Acylation/ipso Heck Reactiona

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a

Run on a 0.3 mmol scale (0.1 M) for 14 h with 1.8 equiv of 27a, 1.0 equiv of 3, 1.5 equiv of t-butyl acrylate, 2.0 equiv of NBE and 3.0 equiv of Cs2CO3; all yields are isolated yields.