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. 2016 Oct 20;8(10):374. doi: 10.3390/polym8100374

Table 2.

Radical (co)polymerizations of DMαHAA with DEAA and the cloud points of the resulting polymer.

Run 1 DMαHAA (mmol) DEAA (mmol) Yield (%) Composition 2 Mn 3 Mw/Mn 3 Tc (°C)
DMαHAA DEAA
3 - 3.12 78 0 100 25,000 1.71 32
10 1.57 6.40 99 6 94 23,000 1.89 34
5 1.65 1.53 57 20 80 1400 2.90 44
11 3.12 1.60 55 40 60 4800 1.77 46
12 6.43 1.63 57 65 35 1700 2.63 64

1 Polymerization was initiated with AIBN (1 mol %) at 60 °C in 1,4-dioxane (3.0 mL) for 16 h; 2 Determined by 1H NMR (400 MHz, CDCl3, 25 °C); 3 Determined by SEC (PS standards, THF, 40 °C).