Table 2.
Run 1 | DMαHAA (mmol) | DEAA (mmol) | Yield (%) | Composition 2 | Mn 3 | Mw/Mn 3 | Tc (°C) | |
---|---|---|---|---|---|---|---|---|
DMαHAA | DEAA | |||||||
3 | - | 3.12 | 78 | 0 | 100 | 25,000 | 1.71 | 32 |
10 | 1.57 | 6.40 | 99 | 6 | 94 | 23,000 | 1.89 | 34 |
5 | 1.65 | 1.53 | 57 | 20 | 80 | 1400 | 2.90 | 44 |
11 | 3.12 | 1.60 | 55 | 40 | 60 | 4800 | 1.77 | 46 |
12 | 6.43 | 1.63 | 57 | 65 | 35 | 1700 | 2.63 | 64 |
1 Polymerization was initiated with AIBN (1 mol %) at 60 °C in 1,4-dioxane (3.0 mL) for 16 h; 2 Determined by 1H NMR (400 MHz, CDCl3, 25 °C); 3 Determined by SEC (PS standards, THF, 40 °C).