|
instantaneous consumption rate of monomer (kmol/s) |
|
Forward rate coefficient for reaction, rth
|
|
molar concentrations of surface-adsorbed species on the catalyst active site |
|
rate exponent for the ith gas phase reactant |
|
rate exponent for the jth gas phase reactant |
|
gas phase species |
|
solid phase species |
|
net molar rate of production in bubble phase |
|
net molar rate of production in emulsion phase |
|
net molar rate of production of catalyst active side for any phase |
U0
|
Superficial gas velocity m/s |
|
stoichiometric coefficient for each reactant species in bubble phase |
|
stoichiometric coefficient for produced PP in bubble phase |
|
stoichiometric coefficient for produced PP in emulsion phase |
|
stoichiometric coefficient for each reactant species in emulsion phase |
|
stoichiometric coefficient for each reactant species on catalyst active site |
|
stoichiometric coefficient for produced PP on catalyst |
|
monomer conversion rate |
|
number of active site types |
|
i-th component |
|
propagation rate coefficient for a site of type j with terminal |
|
reactor volume(m3) |
|
void fraction of the bed at minimum fluidization |
|
superficial gas velocity (m/s) |
|
cross sectional area of the reactor(m2) |
|
concentration of component i in the inlet gaseous stream |
|
volumetric polymer phase out flow rate from the reactor (m3/s) |
|
instantaneous rate of reaction for monomer i (kmol/s) |
|
specific heat capacity of component i (J/kg K) |
|
density of mixed gas density(kg/m3) |
|
specific heat capacity of solid product (J/kg K) |
|
temperature of the inlet gaseous stream (K) |
|
Average temperature in the bed at (K) during
|
|
production rate (kg/s) |
|
Average density of emulsion phase |
|
phase variable |
|
phase volume fraction |
|
the phase density |
|
phase velocity |
|
the diffusion term |
|
the source term |
E |
Phase energy |
|
effective thermal conductivity |
|
volumetric heat sources |
|
net rate of production of species i
|
|
rate of i, species transport |
j |
Jth item (either a reactant or a product). |
|
bubble to emulsion heat transfer coefficient(W/m3 K) |
|
bubble velocity (m/s) |
|
polymer density(kg/m3) |
|
specific heat capacity of solid product (J/kg K) |
|
void fraction of bubble for Geldart B particles |
|
polymer density(kg/m3) |
|
specific heat capacity of solid product (J/kg K) |
|
heat of reaction (J/kg) |
|
volume fraction of bubbles in the bed |
|
“I” monomer concentration (molMe/m3) |
P0
|
active sites concentration (kmol/m3) |
N(0, j) |
uninitiated site of type j produced by formation reaction |
N(r,j) |
living polymer molecule of length r, growing at an active site of type j, with terminal monomer M |
NH(0,j)
|
uninitiated site of type j produced by transfer to hydrogen reaction |
r |
number of units in polymer chain |
kfm
(j)
|
transfer rate coefficient for a site of type j with terminal monomer M reacting with monomer M |
kfcat
(j)
|
transfer rate coefficient for a site of type j with terminal monomer M reacting with catalyst |
kh
(j)
|
rate coefficient for reinitiating of a site of type j by monomer M |
ki
(j)
|
rate coefficient for initiation of a site of type j by monomer M |
kp
(j)
|
propagation rate coefficient for a site of type j with terminal monomer M reacting with monomer M |
PBM |
Population Balance Model |
PMLM |
Polymeric Multilayer Model |
Subscripts and superscripts |
bu
|
bubble phase |
eu
|
emulsion phase |
g |
gas mixture property |
i |
component type number |
in |
inlet |
j |
active site type number |
pol |
polymer |
ref |
reference condition |