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. 2016 Jun 14;8(6):220. doi: 10.3390/polym8060220
r instantaneous consumption rate of monomer (kmol/s)
kf,r Forward rate coefficient for reaction, rth
ct molar concentrations of surface-adsorbed species on the catalyst active site
ηi,g,r rate exponent for the ith gas phase reactant
ηj,s,r rate exponent for the jth gas phase reactant
Ci gas phase species
SJ solid phase species
R i,j(bu) net molar rate of production in bubble phase
R i,j(eu) net molar rate of production in emulsion phase
R i,j(ct) net molar rate of production of catalyst active side for any phase
U0 Superficial gas velocity m/s
Bi,r stoichiometric coefficient for each reactant species in bubble phase
Bi,r stoichiometric coefficient for produced PP in bubble phase
Ei,r stoichiometric coefficient for produced PP in emulsion phase
Ei,r stoichiometric coefficient for each reactant species in emulsion phase
Ci,r stoichiometric coefficient for each reactant species on catalyst active site
Ci,r stoichiometric coefficient for produced PP on catalyst
^i,p monomer conversion rate
Nas number of active site types
Mi i-th component
kp propagation rate coefficient for a site of type j with terminal
VR reactor volume(m3)
εmin void fraction of the bed at minimum fluidization
U0 superficial gas velocity (m/s)
A cross sectional area of the reactor(m2)
[Mi]in concentration of component i in the inlet gaseous stream
Rv volumetric polymer phase out flow rate from the reactor (m3/s)
Ri,p instantaneous rate of reaction for monomer i (kmol/s)
Cpi specific heat capacity of component i (J/kg K)
ρpp density of mixed gas density(kg/m3)
Cp,sol specific heat capacity of solid product (J/kg K)
Tin temperature of the inlet gaseous stream (K)
Tr Average temperature in the bed at (K) during εmin
Rp production rate (kg/s)
ρeu Average density of emulsion phase
φ phase variable
α phase volume fraction
ρ the phase density
υ phase velocity
τ the diffusion term
Sφ the source term
E Phase energy
keff effective thermal conductivity
Sh volumetric heat sources
Ri net rate of production of species i
Si rate of i, species transport
j Jth item (either a reactant or a product).
Hbe bubble to emulsion heat transfer coefficient(W/m3 K)
Ub bubble velocity (m/s)
ρpol polymer density(kg/m3)
Cp,sol specific heat capacity of solid product (J/kg K)
εbu void fraction of bubble for Geldart B particles
ρpol polymer density(kg/m3)
Cp,pol specific heat capacity of solid product (J/kg K)
ΔHR heat of reaction (J/kg)
αbu volume fraction of bubbles in the bed
[Mi] “I” monomer concentration (molMe/m3)
P0 active sites concentration (kmol/m3)
N(0, j) uninitiated site of type j produced by formation reaction
N(r,j) living polymer molecule of length r, growing at an active site of type j, with terminal monomer M
NH(0,j) uninitiated site of type j produced by transfer to hydrogen reaction
r number of units in polymer chain
kfm (j) transfer rate coefficient for a site of type j with terminal monomer M reacting with monomer M
kfcat (j) transfer rate coefficient for a site of type j with terminal monomer M reacting with catalyst
kh (j) rate coefficient for reinitiating of a site of type j by monomer M
ki (j) rate coefficient for initiation of a site of type j by monomer M
kp (j) propagation rate coefficient for a site of type j with terminal monomer M reacting with monomer M
PBM Population Balance Model
PMLM Polymeric Multilayer Model
Subscripts and superscripts
bu bubble phase
eu emulsion phase
g gas mixture property
i component type number
in inlet
j active site type number
pol polymer
ref reference condition