Table 2.
Sample | Mw(SLS) a × 104 (g/mol) | Nagg b | Rg c (nm) | Rh d (nm) | Rg/Rh | A2 e (cm3mol/g2) × 10−4 | dn/dCp f (mL/g) | d g (g/cm3) |
---|---|---|---|---|---|---|---|---|
P20M190 | 5.73 | 1 | 22.2 | 4.3 | 5.14 | 8.13 | 0.166 | 0.286 |
P20A196 | 5.86 | 1 | 21.1 | 4.4 | 4.83 | 12.4 | 0.141 | 0.273 |
PICsome h | 45,000 | 7770 | 87.0 | 78.0 | 1.12 | 2.34 | 0.161 | 0.376 |
a Apparent weight-average molecular weight estimated from static light scattering (SLS). b Aggregation number of PICsomes calculated by dividing Mw(SLS) with that of unimers. c Radius of gyration estimated from SLS. d Hydrodynamic radius estimated from dynamic light scattering (DLS). e Second virial coefficient estimated from SLS. f Refractive index increment. g Density of polymers and PICsomes calculated from Equation (5). h PICsome composed of P20M190 and P20A196 with f+ = 0.5.