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. 2016 Aug 4;8(8):281. doi: 10.3390/polym8080281

Table 3.

A brief record of epoxy-based nanocomposites studied for improvement in electrical conductivity values. HSM: high speed mixing.

Sr. Authors Year Reinforcement/wt % Dispersion method % Increase in electrical conductivity Remarks Ref.
1 Wu et al. 2015 GNPs (1.5 wt %), transverse to alignment Sn + 3RM 1 × 107 The maximum thermal conductivity was observed in the case of aligned GNPs. [229]
GNPs (3 wt %), randomly oriented 1 × 108
GNPs (3 wt %), parallel to alignment 1 × 1010
2 Liu et al. 2015 Graphene woven fabric (GWF) (0.62 wt %) None. 1 × 1013 (Samples were produced using resin infiltration.) The average number of graphene layers in GWFs varied between 4 and 12. [230]
3 Ming et al. 2015 Graphene foam (GF) (80 wt %) None. 8 × 102 (Samples were produced using hot pressing.) The electrical conductivity of pure graphene foam (GF) is 2.9 S-cm-1, which is much lower than graphene, which can be because of the presence of structural defects. [231]
5 Ghaleb et al. 2014 GNPs (1.1 wt %) Sn 1.39 × 106 GNPs are more effective in improving the thermal conductivity of epoxy than MWCNTs. [159]
MWCNTs (1.9 wt %) 1.62 × 105
6 Tang et al. 2014 GO (5 wt %) Sn + HSM 1.92 × 109 The surface functionalization of GO can significantly improve the electrical conductivity of GO–epoxy. [232]
Diamine polyetheramine functionalized GO (GO-D230) (5 wt %) 1.92 × 1012
7 Dou et al. 2014 Silver plated graphene (Ag-G) (25 wt %) Sn + MS 4.13 × 102 Ag–graphene can be used in electronic applications due to its high electrical conductivity. [233]
8 Tang et al. 2014 GO (3.6 wt %) Sn 1 × 1018 The surface functionalization significantly improves electrical conductivity. [234]
Polyetheramine refluxed GO (GO-D2000) (3.6 wt %) 1 × 1017
9 Monti et al. 2013 GNPs (3 wt %) Sn + MS 2.08 × 105 The samples were produced using chloroform. [235]
GNPs (3 wt %) 1.16 × 105 The samples were produced using tetrahydrofuran.
10 Wajid et al. 2013 GNPs (0.24 wt %) Sn + MS 2.22 × 103 The samples were produced using dimethylformamide. [189]
11 Chandrakekaran et al. 2013 GNPs (1 wt %) Sn + ShM 1 × 104 3RM is more effective in improving the electrical conductivity of epoxy than sonication and high speed shear mixing. [73]
GNPs (2 wt %) 3RM 1 × 108
12 Suherman et al. 2013 GNPs (80 wt %), CNTs (5 wt %), through-plane BM + MS 7.30 × 1017 The electrical conductivity significantly increases with hybrid filler. [236]
GNPs (80 wt %), CNTs (5 wt %), in-plane 1.80 × 1018
GNPs (80 wt %), through-plane 4 × 1017
GNPs (80 wt %) in-plane 5 × 1017
13 Mancinelli et al. 2013 GO (0.5 wt %) Sn 240 The conductivity was measured before post-curing. [237]
GO (0.5 wt %) 730 The conductivity was measured after post-curing.
Octadecylamine (ODA)-treated partially reduced and chemically modified GO (MGO) (0.5 wt %) 550 The conductivity was reduced after functionalization.
GO (0.5 wt %) Two phase extraction 240 The system was not fully cured during curing process.
GO (0.5 wt %) 7.80 × 103 The conductivity significantly increased after post-curing.
14 Al-Ghamdi et al. 2013 Foliated graphite nanosheets (FGNs) (40 wt %) Centrifugal mixing 9.90 × 103 Dielectric properties of epoxy–FGN composites decreased with an increase in frequency. [238]
15 Kim et al. 2012 Al(OH)3 functionalized GO (Al-GO) (3 wt %) MS + MgSr 75 The increase in electrical conductivity decreases with Al(OH)3 functionalization of GO. [239]
GO (3 wt %) 115
16 Heo et al. 2012 Al2O3 (80 wt %), Al(OH)3 functionalized GO (Al-GO) (5 wt %) 3RM 2.90 × 103 The increase in electrical conductivity with Al(OH)3 functionalization decreased. The electrically insulating Al(OH)3 on the graphene oxide nanosheet can prevent electron tunneling and act as ion traps which block ion mobility, resulting in a decrease in the electrical properties of nanocomposites. [224]
Al2O3 (80 wt %), GO (5 wt %) 4.90 × 103
17 Tien et al. 2011 Graphite flakes (14 wt %) Sn 4 × 107 The percolation threshold was 8 wt %. [227]
18 Fan et al. 2009 GNPs (5 wt %) Sn + MS 5.50 × 1010 The maximum electrical conductivity was observed in the case of hybrid fillers. [240]
GNPs (4.5 wt %), carbon black (CB) (0.5 wt %) 5.50 × 1012
19 Jovic et al. 2008 Expanded graphite (EG) (8 wt %) Sn 5.50 × 1017 The electrical conductivity further increases with the application of electric field. [241]
20 Li et al. 2007 MWCNTs (1 wt %) Sn 4.63 × 107 The samples were produced using acetone. [242]
21 Pecastaings et al. 2004 MWCNTs (20 wt %) Sn + MS 4.53 × 103 The samples were produced using acetone. [243]