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(a) View of the coordination environments of Zn center in 3 with labeling schemes. Symmetry codes: (A) 1 − x, 1/2 + y, 1 − z; (B) 1 + x, 1 + y, z; (b) View of the 1D [Zn(bpmb)]n chain in 3; (c) View of the 2D structure in 3 looking down b-axis; (d) Schematic view of the six-connected 41263 net of 3. Atom color codes: Zn, cyan; O, red; N, blue; C, dark green and pink. All H atoms are omitted for clarity.
