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Amounts and TON values corresponding to H2 evolved during the reductive water splitting reaction using photocatalysts 1–8, which contain [Zn(bpy)3]2+, [Cu(bpy)3]2+, [Ru(bpy)3]2+ and [Os(bpy)3]2+ complex cations incorporated in (a) {[LiRu(C2O4)3]2−}n and (b) {[NaRu(C2O4)3]2−}n networks under 8 h of Vis (≥417 nm) light irradiation (left). Photoreaction mixtures contained 10 µmol of heterogeneous catalyst, 7 mL of TEA and 10 mL of H2O. TON = μmol of H2 produced/10 μmol of catalyst.
