Table 3.
Entry | Substrate | Catalyst loading, mg | Substrate/Pd (mol/mol) | P (H2), atm. | Conv., % | TOF, h−1 |
---|---|---|---|---|---|---|
1 | Styrene | 0.5 | 41590 | 10 | 62 | 103140 |
2 | 0.5 | 41590 | 30 | 100 | 166365 | |
3 | 0.5 | 103970 | 30 | 50 | 207945 | |
4 | 4‐methylstyrene | 0.5 | 14465 | 10 | 100 | 57870 |
5 | 0.5 | 21700 | 10 | 33 | 28645 | |
6 | 0.5 | 21700 | 30 | 64 | 55555 | |
7 | 4‐tert‐butylstyrene | 0.5 | 27750 | 10 | 80 | 88805 |
8 | 0.5 | 27750 | 30 | 95 | 105455 | |
9 | 0.5 | 41625 | 10 | 22.5 | 37465 | |
10 | 0.5 | 41625 | 30 | 88 | 146525 | |
11 | 4‐phenylstyrene | 1 | 2645 | 10 | 4 [b] | 105 |
12 | trans‐stilbene | 1 | 2645 | 10 | 6 [b] | 160 |
[a] Reaction conditions are: 80 0C, 15 min. [b] 1 h.