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. 2019 Mar 28;8(3):358–381. doi: 10.1002/open.201800280

Table 3.

Hydrogenation of styrenes in the presence of G3‐dendr‐SiO2‐Pd catalyst.[a]

Entry Substrate Catalyst loading, mg Substrate/Pd (mol/mol) P (H2), atm. Conv., % TOF, h−1
1 Styrene 0.5 41590 10 62 103140
2 0.5 41590 30 100 166365
3 0.5 103970 30 50 207945
4 4‐methylstyrene 0.5 14465 10 100 57870
5 0.5 21700 10 33 28645
6 0.5 21700 30 64 55555
7 4‐tert‐butylstyrene 0.5 27750 10 80 88805
8 0.5 27750 30 95 105455
9 0.5 41625 10 22.5 37465
10 0.5 41625 30 88 146525
11 4‐phenylstyrene 1 2645 10 4 [b] 105
12 trans‐stilbene 1 2645 10 6 [b] 160

[a] Reaction conditions are: 80 0C, 15 min. [b] 1 h.