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Unimolecular fragmentation reactions of peroxy radicals. (a) OH loss following H-abstraction from a carbon with a −OOH group attached. (b) NO2 loss following H-abstraction from a carbon atom with a ONO2 group attached. (c) HO2 loss following H-abstraction from a carbon atom with an OH group attached (and subsequent O2 reaction). (d) CO loss following H-abstraction from an aldehydic carbon atom. (e) Epoxide formation.
