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. 2019 Feb 25;119(6):3472–3509. doi: 10.1021/acs.chemrev.8b00395

Table 3. Determined Molar HOM Yields Using NO3 Ionization.

compound total yield (%) due to O3 (%) due to OH (%)a ref
isoprene 4b 0.01 ± 0.005 0.03 ± 0.015 Jokinen et al. 2015100
        Ng et al. 2008147
     
cyclopentene 4.8 ± 0.2     Berndt et al. 201545
     
cyclohexene 4 ± 2     Ehn et al. 20145
  4.5 ± 3.8     Rissanen et al. 201482
  6.0 ± 0.1 (7.3 ± 0.2)c     Berndt et al. 201545
     
cycloheptene 5.9 ± 0.1     Berndt et al. 201545
     
cyclooctene 5.9 ± 0.1     Berndt et al. 201545
     
α-pinene 7.0 ± 3.5     Ehn et al. 20145
  3.4 ± 1.0 3.4 ± 1.7 0.44 ± 0.22 Jokinen et al. 2015100
    1.2 (+1.2/–0.72) 1.2 (+1.2/–0.72) Kirkby et al. 201683
     
limonene 17.0 ± 8.5 5.3 ± 2.7 0.93 ± 0.47 Ehn et al. 20145
        Jokinen et al. 2015100
     
β-pinene <0.1 0.12 ± 0.06 0.58 ± 0.29 Ehn et al. 20145
        Jokinen et al. 2015100
     
myrcene   0.47 ± 0.29 0.14 ± 0.07 Jokinen et al. 2015100
     
β-caryophyllene 1.7 ± 1.28     Jokinen et al. 2016134
  0.5 ± 0.3     Richters et al. 2016170
  1.8 ± 0.9c     Richters et al. 2016170
     
α-cedrene 0.6 ± 0.3     Richters et al. 2016170
  0.6 ± 0.3c      
     
α-humulene 1.4 ± 0.7     Richters et al. 2016170
     
benzene     0.2d Molteni et al. 201885
     
toluene     0.1d Molteni et al. 201885
     
ethylbenzene     0.2d Molteni et al. 201885
     
(o/m/p)-xylene     1.0–1.7d Molteni et al. 201885
     
mesitylene     0.6d Molteni et al. 201885
     
naphthalene     1.8d Molteni et al. 201885
     
biphenyl     2.5d Molteni et al. 201885
a

Deduced by using an OH scavenger in an ozonolysis experiment.

b

Determined using CF3O ionization.

c

Determined using acetate ionization.

d

Pure OH experiments. Note that almost all the experiments have been done at room temperature 20 ± 5 °C.