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. Author manuscript; available in PMC: 2020 Mar 18.
Published in final edited form as: Angew Chem Int Ed Engl. 2019 Feb 15;58(12):4002–4006. doi: 10.1002/anie.201812227

Scheme 1.

Scheme 1.

Olefin Scope. [a]1a (0.1 mmol), alkene (0.15 or 0.3 mmol), quinuclidine (0.2 mmol), [Ir(dF-CH3-ppy)2(dtbbpy)PF6] (2.0 mol%), DMF (0.2M), 34 W blue LED, ~ 40 °C, 16h. [b]Yield of isolated products. [c]dr was determined by 1H NMR of isolated product. [d]1.2 equiv. of 3-buten-2-one was used. [e]0.3 mmol scale. fEWG = electron withdrawing group; Ph = phenyl.