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. 2019 Apr 1;10:1462. doi: 10.1038/s41467-019-09449-7

Table 2.

Conversion and product selectivity in MTO reaction with and without H13CHOa

Feed composition MeOH MeOH + 5 C% H13CHO
Conversion (C%) 88.8 75.8
Product selectivity (C%)
Ethene 3.0 8.6
Propene 36.9 28.1
Butene 20.3 15.8
Dienesb 0.4 0.7
Aromatics 2.4 12.2
C1-4 alkanes 3.1 2.8
C5+ aliphatics 20.2 20.1

aReaction conditions: H-ZSM-5 (Si/Al 90 steamed), W/F 1.82 h·gcat·mol(MeOH+HCHO)−1, MeOH 180 mbar, H2O 60 mbar, or MeOH 171 mbar, H13CHO 9 mbar, H2O 60 mbar, 475 °C

bButadiene and pentadiene