Skip to main content
. 2019 Jan 7;30(4):639–646. doi: 10.1007/s13361-018-2120-x

Table 2.

Observed TiO2-Photocatalyzed Oxidation Products of Buspirone, and Their CID MS/MS Product Ions. A Background-Subtracted Mass Spectrum Is Given in Figure S2b and CID MS/MS Spectra of Buspirone and Photocatalyzed Oxidation Products Are Provided in Figure S4

Photocatalytic oxidation product [M+H]+ Observed CID MS/MS product ions (m/z)
A B C D E F G Other
Buspirone 386.255 222.149 150.103 122.072 265.191
M+O 402.254 222.149 251.176 122.072 265.192 384.240
M+O-H2 400.241 122.072 279.170 150.067 372.240
M-H2 384.240 222.149 162.090
M+2O 418.253 122.072 150.067 177.114
330.192
372.239
384.239
Inline graphic
Proposed CID fragmentation pattern of buspirone