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. Author manuscript; available in PMC: 2019 Aug 13.
Published in final edited form as: J Am Chem Soc. 2019 Jan 30;141(6):2211–2214. doi: 10.1021/jacs.8b12565

Figure 2.

Figure 2.

(A) Alternative proposal of the albomycin biosynthesis. (B) LC–MS analysis of the metabolites from the ΔabmJ strain. Extracted ion chromatogram (EIC) traces corresponding to [M + H]+ signals from 1 or 22 are shown. (C) NOESY analysis and phosgene derivatization of the digested compounds. (D) Reaction of 26/27 with AbmH and AbmD to afford 28 and 29. (E) Reaction of 30/31 with AbmH.