Table 3.
Adsobent-Adsorbate | C- end-otoxin | E- end-otoxin | C- TcdA# | E- Tcd A | C-Stx-2B† | E- Stx-2B† | C- TcdB | E- TcdB |
---|---|---|---|---|---|---|---|---|
Equation | ||||||||
H | ‡ | ‡ | ‡ | ‡ | ‡ | ‡ | ‡ | ‡ |
KH | 1.41.103 | 86.8 | — | 2.117 | 3.303 | 0.055 | 1.049 | 0.658 |
R2 | 0.504 | 0.686 | — | 0.740 | 0.558 | 0.600 | 0.881 | 0.745 |
L | √ | ‡ | ‡ § | § | § | § | § | § |
a = qmKL | 4.27.105 | 83.4 | neg | 7.312 | 0.928 | 0.0022 | 0.549 | 0.213 |
b = KL | 4.79 | neg | neg | neg | neg | neg | neg | neg |
R2 | 0.968 | 0.687 | 0.859 | 0.952 | 0.980 | 0.899 | 0.932 | 0.927 |
F | ‡ | ‡ | ‡ § | √ | √ | ‡ | √ | √ |
KF | 5.04.103 | 68.0 | 71.3 | 6.038 | 0.0028 | 6.41.10−8 | 0.0608 | 4.40.10−4 |
1/n | 0.315 | 1.126 | — | 0.481 | 3.41 | 4.165 | 1.839 | 3.12 |
R2 | 0.886 | 0.690 | 0.797 | 0.952 | 0.9906 | 0.700 | 0.932 | 0.940 |
T | √ | ‡ | § | ‡ | § | § | ‡ | § |
a | 4.48.105 | 3950 | — | 29.3 | 141 | 130 | 1.117 | 42.3 |
b | 4.64 | 2010 | — | 0.974 | neg | neg | 2.21.10−5 | −39.7 |
t | 0.955 | 2.00 | — | 0.500 | 6.568 | 1.778 | 0.0004 | 2.32 |
R2 | 0.968 | 0.686 | — | 0.834 | 1.000 | 0.967 | 0.8814 | 1.000 |
L-S | § | § | § | § | § | § | § | |
a | 0.751 | neg | neg | neg | neg | 1.16.105 | neg | 4.784 |
b | neg | 0.0087 | 0.027 | 0.146 | 0.0129 | neg | 0.139 | neg |
c | neg | 0.441 | 0.178 | 0.439 | 19.1 | neg | 136 | neg |
R2 | 0.904 | 0.807 | 0.908 | 0.952 | 0.990 | 0.967 | 0.939 | 0.948 |
L-F | √ | § | ‡ | § | § | ‡ § | § | § |
a | 4.04.105 | 0.106 | — | — | 103 | — | 2.412 | 2.538 |
b | 4.50 | 0.0001 | — | — | −0.0026 | — | −2.156 | −1.917 |
n | 0.977 | 5.571 | — | — | 2.93 | — | 0.028 | 0.0734 |
R2 | 0.968 | 0.774 | — | — | 0.992 | — | 0.963 | 0.936 |
neg – negative value of the parameter; - no meaningful approximation.
†These data were also fit with the Sigmoidal Hill three-parameter equation: y = axn/(cn + xn): a = 1.23.106, c = 174 and n = 3.41, R2 = 0.989.
√The equation fits the experimental data with R2 > 0.9.
‡The equation does not fit the experimental data.
§The equation fits the experimental data but the negative value for b means also negative values for qm or KL, or both, which does not have a physical meaning.
#These data fit with the three-parameter equation: y = x/(a + bxn), a = 0.024, b = 0.00826, n = 2.36, R2 = 0.925.