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. 2019 Apr 5;6(2):024901. doi: 10.1063/1.5090332

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© 2019 Author(s).

2329-7778/2019/6(2)/ 024901/8

All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).

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FIG. 2. — (a) Partial ionization cross sections for the Fe 1s, 2s,p, and 3s,p,d shells through absorption of 7200 eV photons²⁶ and through electron-impact.²⁸ (b) Simulated energy and time distributions of incident photons as well as energetic photo- and Auger electrons released in the studied material under irradiation with one X-ray pulse with a flux of 244 × 10³⁰ photon/(s cm²). The data for electrons were integrated over 500 eV energy intervals and 5 fs time periods. The data for photons were integrated over 5 fs time intervals. (c) Illustration of the unique high valence state creation process on the metal site in a Fe(CN)₆ molecule under ultrashort intense X-ray pulse irradiation.