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. 2019 Apr 5;9:5736. doi: 10.1038/s41598-019-42236-4

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© The Author(s) 2019

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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NEXAFS spectroscopy. (a) B K-edge spectra and (b) N K-edge spectra of the h-BN film grown on the Ni(111) for different incident angles θ (the angle between the sample plane and the X-ray propagating direction, as marked in the figure). (c) B K-edge spectra of the h-BN films grown on the Ni(111) and sapphire, measured at the incident angle θ of 30°. (Inset) Magnified spectra in the range between 190 eV and 194 eV for showing the low-energy shoulder A₁, the high-energy shoulders A₂, A₃.