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. 2019 Mar 27;19(4):506–516. doi: 10.1089/ast.2017.1800

FIG. 2.

FIG. 2.

Possible prebiotic reactions involving volcanic SO2, HCHO, and other lower carbohydrates. Note how the reaction with ribose involves competition with ring closed forms, here the furanose. Therefore, the equilibrium concentration favors the bisulfite addition product with ribose considerably less than with HCHO, glycolaldehyde, or glyceraldehyde. The same is the case with ketoses. The stereochemistry shown is arbitrary.