Table 2. Scope of arenes for the photoelectrocatalytic arene C-H amination.^a.

3, 10 h, 77% o:p = 6:1	4b, 10 h, 65% o:p = 7:1	5, 10 h, 56% o:p = 4:1	6c, 15 h, 66 % o:p = 5:1
7c, 15 h, 86 % o:p = 4:1	8b, 10 h, 71% o:p = 3:1	9b,c, 15 h, 50%	10c, 8 h, 77%
11c,d, 10% (10 h) 37% (24 h), 45% (36 h)	12b,c, 24 h, 54%	13, 10 h, 56%	14b, 10 h, 51%
15c, 15 h, 52%	16c, 24 h, 48% P1:P2 =2:1	17c, 24 h, 89% P1:P2 =3:1	18c, 10 h, 82% P1:P2 =2:1
19b,c, 24 h, 50%	20c,10 h, 78% P1:P2 = 3:1	21, 10 h, 62%	22, 10 h, 60%

^[a]Reaction conditions: Substrate (0.2 mmol) in HFIP/MeOH (4:1, 3 mL) at ambient temperature. Isolated yields.

^[b]Applied potential: E = 0.83 V vs Fc/Fc⁺

^[c]Azoles (0.6 mmol, 3 equiv.) was added.

^[d]Applied potential: E = 1.03 V vs Fc/Fc⁺. HFIP/H₂O (9:1, 3 mL) was used.