Table 6.
Component | Comment | Type | ui% | |
---|---|---|---|---|
Massic activity | Standard uncertainty of replicate IDAS measurements of 229Th massic activity | A | 0.69 | |
Weighing | Estimated relative uncertainty for potential bias in mass of IDAS solution aliquots | B | 0.30 | |
Peak tail | Estimated uncertainty of 229Th peak tail correction applied to the α count data | B | 0.21 | |
230Th spike | Combined standard uncertainty of the massic activity for SRM 4342A | B | 0.20 | |
Background | Estimated uncertainty of 229Th and 230Th background corrections | B | 0.04 | |
Relative combined standard uncertainty (uc) | 0.81% | |||
229Th massic activity (Bq g−1) | Expanded uncertainty (Bq g−1) | |||
195.9 | 3.2 (Relative: 1.6%) |
The uncertainty estimate for the massic activity was calculated in accordance with Taylor and Kuyatt, [20] and GUM protocols [21] using the GUM Workbench software [22]. ui% represents the relative standard uncertainty for the listed components. The expanded uncertainty (U = k × uc) for the massic activity value is the product of the combined standard uncertainty (uc) and a coverage factor (k), with k = 2 to achieve an approximately 95% level of confidence