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. Author manuscript; available in PMC: 2019 Apr 11.
Published in final edited form as: J Radioanal Nucl Chem. 2018;318:10.1007/s10967-018-6032-9. doi: 10.1007/s10967-018-6032-9

Table 6.

Uncertainty Budget for 229Th massic activity by IDAS

Component Comment Type ui%
Massic activity Standard uncertainty of replicate IDAS measurements of 229Th massic activity A 0.69
Weighing Estimated relative uncertainty for potential bias in mass of IDAS solution aliquots B 0.30
Peak tail Estimated uncertainty of 229Th peak tail correction applied to the α count data B 0.21
230Th spike Combined standard uncertainty of the massic activity for SRM 4342A B 0.20
Background Estimated uncertainty of 229Th and 230Th background corrections B 0.04
Relative combined standard uncertainty (uc) 0.81%
229Th massic activity (Bq g−1)    Expanded uncertainty (Bq g−1)
195.9    3.2 (Relative: 1.6%)

The uncertainty estimate for the massic activity was calculated in accordance with Taylor and Kuyatt, [20] and GUM protocols [21] using the GUM Workbench software [22]. ui% represents the relative standard uncertainty for the listed components. The expanded uncertainty (U = k × uc) for the massic activity value is the product of the combined standard uncertainty (uc) and a coverage factor (k), with k = 2 to achieve an approximately 95% level of confidence