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. Author manuscript; available in PMC: 2019 Apr 15.
Published in final edited form as: Biomacromolecules. 2016 Aug 26;17(9):2830–2838. doi: 10.1021/acs.biomac.6b00615

Table 2. Effect of solvent concentration upon the copolymerization of EGDPEA:DEGMA with a relative monomer molar feed concentration of 75%:25% conducted using CCTP.

Entry Monomer/DCM % ratio Temp (°C) Time (h) EGDPEA Conv (%) DEGMA Conv (%) Overall Conv (%) Mn (g mol-1) Ð
1 100:0 40 1 Gelation
2 100:0 35 3 Gelation
3 25:75 35 24 45 47 46 27500 1.69
4 75:25 35 24 44 66 48 58500 3.63
5 50:50 35 24 47 58 50 35000 2.52
6 25:75 35 48 68 94 75 41000 2.96