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. Author manuscript; available in PMC: 2019 Dec 21.
Published in final edited form as: Org Lett. 2018 Dec 11;20(24):8082–8085. doi: 10.1021/acs.orglett.8b03439

Table 1.

Products 7a from reactionsb between benzyne precursors 6a-f and diaziridines 2a-h.

graphic file with name nihms-1002778-t0007.jpg
a

The structure number of each product contains two letters, the first indicating the poly-yne 6 and the second the diaziridine 2 of origin.

b

All reactions were performed in benzene having an initial [6] = 0.02 M and [2] = 0.04 M. Solutions were heated at 85–90 °C (external bath T) for 18-19 h, except for the case of the less reactive 6e, where the reaction time was 48 h.