Table 4.
Overview of the compound specific MS/MS parameters for mycotoxins, measured in the ESI positive mode.
| Name | Measured Form/Adduct | Precursor Ion (m/z) | Quantifier Ion (m/z) | Qualifier Ion (m/z) | Cone Voltage (V) | Collision Energy (eV) (a-b) | Retention Time (min) |
|---|---|---|---|---|---|---|---|
| DON | [M + H]+ | 297.0 | 249.1 | 203.4 | 20 | 9-14 | 4.36 |
| DOM1 | [M + H]+ | 281.0 | 215.0 | 233.0 | 30 | 12-12 | 4.70 |
| 3/15-ADON | [M + H]+ | 339.2 | 213.1 | 230.9 | 25 | 12-8 | 5.02 |
| T2 | [M + NH4]+ | 484.0 | 215.2 | 304.8 | 26 | 18-15 | 8.24 |
| HT2 | [M + NH4]+ | 442.0 | 263.0 | 215.1 | 20 | 10-10 | 7.01 |
| T2-G | [M + NH4]+ | 646.0 | 245.0 | 215.3 | 35 | 20-22 | 7.20 |
| AFB1 | [M + H]+ | 313.0 | 285.1 | 241.1 | 35 | 23-34 | 5.63 |
| AFM1 | [M + H[+ | 328.9 | 272.9 | 229.0 | 30 | 20-35 | 5.18 |
| OTA | [M + H]+ | 404.0 | 238.9 | 220.8 | 35 | 20-32 | 9.23 |
| ENN A1 | [M + H]+ | 668.2 | 210.1 | 227.9 | 80 | 20-20 | 12.96 |
| ENN A | [M + Na]+ | 704.5 | 350.1 | 232.2 | 35 | 48-48 | 13.12 |
| ENN B | [M + H]+ | 640.1 | 213.8 | 527.2 | 80 | 22-21 | 12.69 |
| ENN B1 | [M + NH4]+ | 671.5 | 196.2 | 214.3 | 30 | 28-28 | 12.84 |
| BEA | [M + H]+ | 784.1 | 244.0 | 262.1 | 80 | 25-30 | 12.81 |
| FB2 | [M + H]+ | 706.10 | 318.2 | 336.2 | 60 | 35-42 | 10.07 |
| [13C15]-Deoxynivalenol | [M + H]+ | 312.0 | 263.0 | 245.0 | 20 | 10-10 | 4.37 |
| [13C17]-Aflatoxin B1 | [M + H]+ | 330.10 | 255.1 | 301.0 | 20 | 35-28 | 5.63 |
| [13C20]-Ochratoxin A | [M + H]+ | 424.0 | 250.0 | 377.1 | 20 | 25-15 | 9.23 |
| [13C24]-T2-toxin | [M + NH4]+ | 508.40 | 229.1 | 198.2 | 25 | 20-20 | 8.24 |
| [13C34]-Fumonisin B1 | [M + H]+ | 756.50 | 356.2 | 374.3 | 15 | 40-35 | 9.67 |
| [15N3]-Enniatin B | [M + H]+ | 643.30 | 197.1 | 215.30 | 80 | 18-18 | 12.69 |
Note: m/z = mass-to-charge ratio; (a-b): collision energy for the quantifier (a) and qualifier ion (b), respectively.