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. Author manuscript; available in PMC: 2019 Oct 24.
Published in final edited form as: J Am Chem Soc. 2018 Oct 15;140(42):13976–13984. doi: 10.1021/jacs.8b09565

Scheme 3.

Scheme 3.

Isolated yields are reported as the average of two runs. Standard reaction conditions: terminal olefin (0.50 mmol), Bn2NOBz (2) (0.60 mmol), Cu(OAc)2 (2.50 mol%), L6 (2.55 mol%), DMMS (1.50 mmol), THF (1.0 mL), 23 °C, 3h. a40 °C. b DTBM-SEGPHOS was used in place of L6 and NMR yields are provided.