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Proposed Decomposition of a Putative NiI Carboxylate Formed from the Reaction of (PPh3)2NiI(2,4,6-iPr3C6H2) with CO2 and Trapping Experiments of the Proposed Decomposition Productsa
aCompounds in brackets were unobserved during the reaction. *74% yield for formation of 2 equiv of (PPh3)2NiIBr of which only 37% of the Ni is presumably from the starting (PPh3)2NiI(2,4,6-iPr3C6H2).
