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. Author manuscript; available in PMC: 2019 Dec 12.
Published in final edited form as: J Am Chem Soc. 2018 Nov 29;140(49):16976–16981. doi: 10.1021/jacs.8b11699

Figure 2.

Figure 2.

Alkyl radicals generated by MHAT add to chiral sulfinimines. d.r. of two major diastereomers reported. astereochemistry at the α-carbon is (S). bstereochemistry in the α-carbon is (R). cMn(dpm)3 instead of Fe(acac)3 was used. dcontains 15% unrearranged pinene product and its diastereomer. e3 equiv. of olefin used.