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. Author manuscript; available in PMC: 2019 Dec 5.
Published in final edited form as: J Am Chem Soc. 2018 Nov 16;140(48):16807–16820. doi: 10.1021/jacs.8b10313

Figure 2.

Figure 2.

Non-phase shifted Fourier transform EXAFS spectra of MMOHred (A), MMOHox (B) and MMOH-RFQ (C) samples. HERFD-EXAFS (black) of M.t. MMOH is compared with the previously published PFY-EXAFS of M.t. MMOH (blue)13 and Mc (Bath) MMOH (orange). 37–38 For the FT-EXAFS from Shu, et al, a phase shift of 0.5 Å for MMOHred and 0.35 Å for MMOHox and MMOH-RFQ (see text) was subtracted from the previously published spectra to obtain a non-phase shifted FT-EXAFS for comparison. The published FT-EXAFS of Rudd et al, had no phase-shift previously applied. PFY-EXAFS of M.t. MMOH from Shu, L.; Nesheim, J. C.; Kauffmann, K.; Münck, E.; Lipscomb, J. D.; Que, L., Jr. Science 1997, 275 (5299), 515. Adapted with permission from AAAS. PFY-EXAFS of M.c. MMOH adapted with permission from Jackson Rudd, D.; Sazinsky, M. H.; Merkx, M.; Lippard, S. J.; Hedman, B.; Hodgson, K. O. Inorg. Chem. 2004, 43 (15), 4579 Rudd, D. J.; Sazinsky, M. H.; Lippard, S. J.; Hedman, B.; Hodgson, K. O. Inorg. Chem. 2005, 44 (13), 4546. Copyright 2004 and 2005 American Chemical Society.