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Asymmetric hydration of 1‐octene on preparative scale. A) Enantioselective hydration of 1‐octene by Em‐OAH A248L using hexanoic acid as a decoy molecule. B) Results of 1‐octene preparative‐scale reaction (red line in GC trace). Upscaling of 1‐octene hydration by Em‐OAH A248L was performed with 56 mg starting material (1 mm 1‐octene) using a whole‐cell catalyst (100 mg mL−1) and hexanoic acid as a decoy molecule.
