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. 2019 Mar 4;10(15):4148–4162. doi: 10.1039/c8sc05496g

Table 1. Summary of EXAFS curve fitting for Pd-based catalysts.

Sample Edge Shell N R (Å) ΔE (eV) σ 22) R-Factor
Pd black Pd K Pd–Pd 12 (fix) 2.74 ± 0.00 0.0 ± 0.3 0.006 0.002
Pd/Al2O3 Pd K Pd–O 0.7 ± 0.2 2.02 ± 0.02 6.4 ± 3.2 0.004 0.002
Pd–Pd 7.1 ± 0.3 2.73 ± 0.00 0.0 ± 0.4 0.009
PdIn/Al2O3 Pd K Pd–In 6.6 ± 0.3 2.73 ± 0.00 0.0 ± 0.3 0.012 0.012
In K In–O 2.5 ± 0.3 2.14 ± 0.01 2.3 ± 1.5 0.010 0.014
In–Pd 5.7 ± 0.6 2.74 ± 0.01 0.0 ± 0.7 0.014
Pd–In–Cu/Al2O3 Pd K Pd–Cu 3.0 ± 0.3 2.60 ± 0.01 1.8 ± 1.6 0.006 0.002
(Pd : In : Cu = 3 : 1 : 2) Pd–In 5.8 ± 0.5 2.70 ± 0.01 –1.3 ± 0.7 0.013
In K In–O 2.6 ± 0.3 2.13 ± 0.01 4.1 ± 1.5 0.010 0.010
In–Pd 5.8 ± 0.5 2.70 + 0.00 0.0 ± 0.6 0.010
Cu K Cu–O 1.0 ± 0.2 1.93 ± 0.02 5.8 ± 2.3 0.006 0.006
Cu–Cu 2.2 ± 1.6 2.58 ± 0.08 –1.0 ± 9.5 0.013
Cu–Pd 3.1 ± 0.9 2.59 ± 0.02 –3.2 ± 0.7 0.009