Table 3.

Tentative identification of anthocyanins and hydroxycinnamic acid glycosides in gooseberry cvs with QToF/MS/MS.

Peak	Ret. time (min)		m/z	Fragments MS/MS	Tentative identification	Molecular formula
Anthocyanins
3	7.13	[M+]	463.1303	301.0995	Peonidin-3-glucoside	C₂₂H₂₃O₁₁
3	7.27	[M+]	419.1190	287.055	Cyanidin-3-xyloside	C₂₀H₁₉O₁₀
4	7.42	[M+]	609.2129	301.0994	Peonidin-3-rutinoside	C₂₈H₃₃O₁₅
6	10.11	[M+]	595.1447	287.055	Cyanidin-glycoside
7	10.36	[M+]	595.1480	(287.0814, 147.0570, 163.1326)	Cyanidin-coumaroyl-glucopyranoside	C₃₀H₂₇O₁₃
8	10.96	[M+]	609.1594	301.705	Peonidin-glycoside	C₂₈H₃₃O₁₅

Ret. time (min)		m/z	Fragments MS/MS	Tentative identification	Molecular formula
Hydroxycinnamic acid derivatives
5.15, 6.10	[M − Na]+	349.0893	(165.0545, 147.0570)	Coumaric acid hexoses	C₁₅H₁₈O₈
4.20	[M − Na]+	365.0862	(181.0508, 163.0402, 145.0283, 135.0437, 117.0333, 89.0383)	Caffeic acid hexose	C₁₅H₁₈O₉
4.86, 6.42	[M − Na]+	379.0999	(195.0651, 177.0546)	Ferulic acid hexoses	C₁₆H₂₀O₉
5.62	[M − Na]+	409.1109	(225.076, 207.0652, 175.0391)	Sinapic acid hexose	C₁₇H₂₂O₁₀