Fig. 4. Molecular structure of germaacyl thioester 10 with thermal ellipsoids at the 50% probability level. All hydrogen atoms are omitted for clarity. Selected bond lengths (Å) and angles (deg): Ge1–O1 1.698(3), O1–B1 1.501(5), Ge1–S1 2.199(2), Ge1–N1 1.864(4), Ge1–N2 1.866(4); O1–Ge1–S1 116.19(1), B1–O1–Ge1 144.0(3), N2–Ge1–N1 85.72(2). Data collection temperature: 100 K.
