Table 2.
Iridium-catalyzed amination of α-methyl allyl acetate 1a with secondary aromatic and heteroaromatic amines 3a-3l to form enantiomerically enriched allylic amines 5a-51.a
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Yields of material isolated by silica gel chromatography. Enantioselectivities were determined by chiral stationary phase HPLC analysis. See Supporting Information for further experimental details.