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Iridium-catalyzed amination of α-substituted allyl acetates 1a-1g with secondary heteroaromatic amine 3m to form enantiomerically enriched allylic amines 6a-6g.a
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Yields of material isolated by silica gel chromatography. Enantioselectivities were determined by chiral stationary phase HPLC analysis. See Supporting Information for further experimental details.
