Table 3.
Conversion of adducts 3a–3j to 4-methylenepyrrolidines 5a–5j via Tsuji-Trost allylation-Mitsunobu cyclization.a
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Yields are of material isolated by silica gel chromatography. See Supporting Information for further experimental details.
After the first reaction was done, PPh3 (500 mol%), DIAD (500 mol%) and THF (0.05 M) were added at 25 °C, 12 h.