Table 3. Summary of reanalysis of Keller’s gaseous He4 isotherms [11].
Isotherm | Units | A | B | C | D | E |
No. of points | 12 | 14 | 12 | 17 | 9 | |
mm Hg | 588.55 | 291.31 | 147.55 | 52.758 | 35.541 | |
T58() | mdeg | 3954.2 | 3339.2 | 2864.0 | 2315.1 | 2147.3 |
P3() | mm Hg | 528.42 | 254.50 | 195.21 | ||
T62[P3()] | mdeg | 2864.0 ± 0.2 | 2315.0 ± 0.2 | 2147.6 ± 0.2 | ||
TWO-CONSTANT FIT | ||||||
Tiso | mdeg | 3953.7 ± 2.1 | 3338.4 ± 2.1 | 2863.5 ± 0.9 | 2316.7 ± 2.3 | 2148.9 ± 0.9 |
B | cm3/mole | −83.97±0.66 | −103.60±0.78 | −124.16±0.63 | − 153.38±4.21 | −176.04±2.04 |
Variance | 8.7 | 17.8 | 3.6 | 23.4 | 1.69 | |
(T58 – Tiso) | mdeg | −1. 5±2.1 | 0.8±2.1 | 0.5±0.9 | −1.6±2.3 | −1.6±0.9 |
(T62 – Tiso) | mdeg | 0.5±1.1 | −1.7±2. 5 | −1.3±1.1 | ||
THREE-CONSTANT FIT | ||||||
Tiso | mdeg | 3953.8±4.3 | 3335.3±3. 7 | 2860.9±1.5 | 2311.9±6.1 | 2146. 5±2.8 |
B | cm3/mole | −82.16±3.52 | −99.80±3.78 | −118.47±2.86 | −132.1 ±25.7 | −162.6±15.8 |
C | cm6/mole2 | −1452±2773 | −3133 ±3042 | −6741 ±3331 | − 50,490±60,020 | −38, 900±45,160 |
Variance | 9.4 | 17.7 | 2.8 | 23.9 | 1.75 |