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. 2019 Apr 17;7:246. doi: 10.3389/fchem.2019.00246

Table 3.

Degree of condensation as evidenced by S/G ratio and condensed: non-condensed G2 ratios of enzymatic mild acidolysis lignin (EMAL) isolated from sugarcane bagasse and for lignins isolated from four agricultural feedstocks with [TEA][HSO4] with 20 wt% water and a biomass to solvent ratio of 1:10 g/g.

Lignin Sub-unit composition S/G ratioa Cond/Non-condb
G2 G2,cond S2 S2,cond
Bagasse EMAL 81.8 18.2 182.5 42.5 1.12 0.18
Wheat straw 170°30′ 55.8 44.2 83.3 41.3 0.62 0.44
Rice straw 170°30′ 47.1 52.9 62.0 34.9 0.48 0.53
Rice husk 170°45′ 54.5 45.5 22.2 17.5 0.20 0.45
Bagasse 170°45′ 42.9 57.1 64.3 57.9 0.61 0.57
a

Calculated from HSQC NMR spectra signals as 0.5(S2 + S2,cond)/(G2 + G2,cond).

b

Calculated as cond/non-cond = G2,cond/(G2 + G2,cond).