Table 2.
Iris chromite compositions from TEM and SEM EDS.
| Normalized Oxide Weight % |
||||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Spectrum | SiO2 | TiO2 | Al2O3 | V2O3 | Cr2O3 | Fe2O3 | MgO | MnO | FeO | t (nm) |
| TEM 24 | 0.00a | 1.80 | 17.90 | 43.99 | 2.85 | 5.69 | 27.78 | 100b | ||
| TEM 25 | 0.00a | 1.19 | 19.03 | 0.48 | 45.04 | 2.18 | 6.15 | 0.81 | 25.13 | 260 |
| TEM 26 | 1.48 | 2.48 | 14.94 | 47.10 | 0 | 5.90 | 28.10 | 150 | ||
| SEM 10 | 0.73 | 1.91 | 14.12 | 0.57 | 45.80 | 3.93 | 5.75 | 0.76 | 26.43 | n/a.c |
| Cations per 4 oxygens |
||||||||||
| Spectrum | Si | Ti | Al | V | Cr | Fe3+ | Mg | Mn | Fe2+ | Fe3+/ΣFe |
| TEM 24 | 0.000 | 0.045 | 0.695 | 1.146 | 0.071 | 0.279 | 0.765 | 0.08 | ||
| TEM 25 | 0.000 | 0.029 | 0.734 | 0.006 | 1.166 | 0.054 | 0.300 | 0.022 | 0.688 | 0.07 |
| TEM 26 | 0.066 | 0.083 | 0.789 | 1.668 | 0.000 | 0.394 | 1.053 | 0.00 | ||
| SEM 10 | 0.024 | 0.048 | 0.558 | 0.008 | 1.213 | 0.099 | 0.287 | 0.022 | 0.741 | 0.12 |
SiO2 contribution removed. If some glass was present in the spectrum, this could influence other elements.
We used a thin film correction based on STXM thickness (t) measurements. Where no STXM measurement was available, we assumed a nominal 100 nm correction.
We used the XPP matrix correction on SEM measurements.